Ytterbium(II) fluoride is a binary inorganic compound of ytterbium and fluorine with the chemical formula .
Ytterbium(II) fluoride can be obtained by reacting ytterbium(III) fluoride with ytterbium or hydrogen.
Ytterbium(II) fluoride is a gray solid and crystallizes in the so-called fluorite type analogous to calcium fluoride with a unit cell a axis of 559.46 pm. In the crystal structure of ytterbium(II) fluoride, the Yb<sup>2+</sup> cation is surrounded by eight F<sup>âÂÂ</sup> anions in the form of a cube, which is tetrahedrally surrounded by four Yb<sup>2+</sup>.