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Strontium disilicide

Strontium disilicide is a binary inorganic compound of strontium and silicon with the chemical formula .

Synthesis

Synthesis of strontium disilicide can be by fusion of strontium oxide or strontium carbonate with silicon, or silicon oxide and with coal:

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Physical properties

Strontium disilicide forms silver-gray crystals of the cubic system, space group P4<sub>1</sub>32. The unit cell parameters are a = 6.540&nbsp;Å. The density is measured at 3.40 kg/l but based on the unit cell size, it should be 3.43&nbsp; kg/l. The silicon atoms form a three-dimensional lattice with the smallest Si-Si distance being 2.41&nbsp;Å which is slightly more than in solid silicon. Si-Si-Si angles ∠ are 113.03°. Each silicon atom connects to three other silicon atoms. Eight silicon atoms surround each strontium atom, six at 3.21&nbsp;Å and two at 3.43&nbsp;Å.

Chemical properties

Water decomposes the compound:

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Also, the compound reacts with mineral acids.

Uses

is reported to be a narrow-gap semiconductor or even a Weyl semimetal, with holes as the dominant charge carriers. The potential applications include thermoelectric devices and other applications where its unique properties can be utilized.

References