Sodium pyrosilicate

Sodium pyrosilicate is the chemical compound . It is one of the sodium silicates, specifically a pyrosilicate, formally a salt of the unstable pyrosilicic acid .

Structure

The anhydrous solid has the triclinic crystal structure, with space group P (a = 5.8007(8) ÃÂ, b = 11.5811(15) Å, c = 23.157(3) Å, α = 89.709(10)°, β = 88.915(11)°, γ = 89.004(11)°, V = 1555.1(4) ų, Z = 8, Dx = 2.615 g·cm^{−3}, μ(Mo‐Kα) = 7.94 cm^{−1}). The anions are arranged in layers parallel to the (100) plane, with the sodium cations distributed in 24 distinct crystallographic positions, coordinated by 4 to 6 near oxygen atoms. Some of the 4-coordinated sodium atoms can be interpreted as parallel columns of edge-sharing tetrahedra. The columnar arrangement forms tunnels that house the remaining sodium cations. Twinning at a microscopic scale simulates a much larger monoclinic C centered lattice (V′ = 6220 ų, Z = 32).

See also

• Sodium metasilicate,
• Sodium orthosilicate,

References