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Silver telluride

Silver telluride (Ag<sub>2</sub>Te) is a chemical compound, a telluride of silver, also known as disilver telluride or silver(I) telluride. It forms a monoclinic crystal. In a wider sense, silver telluride can be used to denote AgTe (silver(II) telluride, a metastable compound) or Ag<sub>5</sub>Te<sub>3</sub>.

Properties

Silver telluride is a semiconductor which can be doped both n-type and p-type. Stoichiometric Ag<sub>2</sub>Te has n-type conductivity. On heating silver is lost from the material.

Non-stoichiometric silver telluride has shown extraordinary magnetoresistance.

Occurrence

Silver(I) telluride occurs naturally as the mineral hessite, whereas silver(II) telluride is known as empressite. A silver gold telluride occurs as sylvanite.

Synthesis

Porous silver telluride (AgTe) is synthesized by an electrochemical deposition method. A potentiostat and a three-electrode cell with sulfuric acid electrolyte containing Ag nanoparticles at are used. A silver paste used in the tungsten ditelluride (WTe<sub>2</sub>) attachment leaches into the electrolyte, causing Ag to dissolve in the electrolyte. The electrolyte is stirred to remove hydrogen bubbles. A silver-silver chloride electrode and a platinum wire can be used as reference and counter electrodes. In order to grow the porous AgTe, the WTe<sub>2</sub> is treated with cyclic voltammetry.

Glutathione-coated Ag<sub>2</sub>Te nanoparticles can be synthesized by preparing a solution containing AgNO<sub>3</sub>, Na<sub>2</sub>TeO<sub>3</sub>, and glutathione. N<sub>2</sub>H<sub>4</sub> is added under stirring in an ice bath. The resulting product is washed for purification.

References

General references

  • Hagyeong Kwon, Dongyeon Bae, Dongyeun Won, Heeju Kim, Gunn Kim, Jiung Cho, Hee Jung Park, Hionsuck Baik, Ah Reum Jeong, Chia-Hsien Lin, Ching-Yu Chiang, Ching-Shun Ku, Heejun Yang, and Suyeon Cho "Nanoporous Silver Telluride for active hydrogen evolution." (n.d.) https://pubs.acs.org/doi/10.1021/acsnano.0c09517