Praseodymium(IV) oxide is an inorganic compound with chemical formula PrO<sub>2</sub>.
Praseodymium(IV) oxide can be produced by boiling Pr<sub>6</sub>O<sub>11</sub> in water or acetic acid:
Praseodymium(IV) oxide starts to decompose at 320~360 ðC, liberating oxygen.