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Paddlane

In organic chemistry, paddlane is any member of a class of tricyclic saturated hydrocarbons having two bridgehead carbon atoms joined by four bridges. The name derives from a supposed resemblance of the molecule to a paddle wheel: namely, the rings would be the propeller's blades, and the shared carbon atoms would be its axis.

Systematically named tricyclo [m.n.o.p<sup>1,m+2</sup>]alkanes, these compounds have been referred to as [m.n.o.p]paddlanes. The notation [m.n.o.p]paddlane means the member of the family whose rings have m, n, o, and p carbons, not counting the two bridgeheads; or m&nbsp;+&nbsp;2, n&nbsp;+&nbsp;2, o&nbsp;+&nbsp;2, and p&nbsp;+&nbsp;2 carbons, counting them. The chemical formula is therefore C<sub>2+m+n+o+p</sub>H<sub>2(m+n+o+p)</sub>. When p&nbsp;=&nbsp;0, the compounds are propellanes.

Compounds

The best known paddlane is [1.1.1.1]paddlane which can be seen as a precursor to octahedrane (C<sub>6</sub>), an allotrope of elemental carbon.

The American chemist Philip Eaton, famous for being the first to synthesize the "impossible" cubane molecule, has conducted studies for the synthesis of [2.2.2.2]paddlane. The first mention of paddlane goes back to 1973.

References

See also