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Nickel formate

Nickel formate is the nickel salt of formic acid with the chemical formula Ni(HCOO)<sub>2</sub>.

Synthesis and structure

Nickel formate can be obtained by reacting nickel(II) acetate or nickel(II) hydroxide with formic acid.

Ni(OH)<sub>2</sub> + 2HCOOH → Ni(HCOO)<sub>2</sub> + 2 H<sub>2</sub>O

Nickel formate can also be synthesized by the reaction of sodium formate with nickel (II) sulphate.

Characteristics

As a dihydrate, nickel formate is a green, odorless, non-flammable solid that is sparingly soluble in water. The compound has a monoclinic crystal structure. The anhydride forms on careful heating at 130–140&nbsp;°C. When heated in a vacuum to 300&nbsp;°C, pure nickel is formed:

Such fine powders are useful as hydrogenation catalysts.

Use

Nickel formate is used in the production of nickel and other nickel compounds such as nickel catalysts.

References