my-server
← Wiki

Halite (oxyanion)

A halite, also known as a halogenite, is an oxyanion containing a halogen in a +3 oxidation state. It is the conjugate base of a halous acid. The known halites are chlorite, bromite, and iodite.

Uses

Halites can be used to generate the respective halogen dioxides via a one-electron oxidation:

5&nbsp;NaClO<sub>2</sub> + 4&nbsp;HCl → 5&nbsp;NaCl + 4&nbsp; + 2&nbsp;H<sub>2</sub>O
+ HBrO<sub>3</sub> + H<sup>+</sup> → 2&nbsp; + H<sub>2</sub>O

This reaction in particular is used in bleach to generate chlorine dioxide.

Stability

Chlorites tend to decompose rapidly, some even explosively, upon heating. A few bromites have been isolated, but no iodites have.

References