Dividing line between metals and nonmetals

The dividing line between metals and nonmetals can be found, in varying configurations, on some representations of the periodic table of the elements (see mini-example, right). Elements to the lower left of the line generally display increasing metallic behaviour; elements to the upper right display increasing nonmetallic behaviour. When presented as a regular stair-step, elements with the highest critical temperature for their groups (Li, Be, Al, Ge, Sb, Po) lie just below the line.

The location and therefore usefulness of the line is debated. It cuts through the metalloids, elements that share properties between metals and nonmetals, in an arbitrary manner, since the transition between metallic and non-metallic properties among these elements is gradual.

Names

This line has been called the amphoteric line, the metal-nonmetal line, the metalloid line, the semimetal line, or the staircase. While it has also been called the Zintl border or the Zintl line these terms instead refer to a vertical line sometimes drawn between groups 13 and 14. This particular line was named by Laves in 1941. It differentiates group 13 elements from those in and to the right of group 14. The former generally combine with electropositive metals to make intermetallic compounds whereas the latter usually form salt-like compounds.

History

References to a dividing line between metals and nonmetals appear in the literature as far back as at least 1869. In 1891, Walker published a periodic "tabulation" with a diagonal straight line drawn between the metals and the nonmetals. In 1906, Alexander Smith published a periodic table with a zigzag line separating the nonmetals from the rest of elements, in his highly influential textbook Introduction to General Inorganic Chemistry. In 1923, Horace G. Deming, an American chemist, published short (Mendeleev style) and medium (18-column) form periodic tables. Each one had a regular stepped line separating metals from nonmetals. Merck and Company prepared a handout form of Deming's 18-column table, in 1928, which was widely circulated in American schools. By the 1930s Deming's table was appearing in handbooks and encyclopaedias of chemistry. It was also distributed for many years by the Sargent-Welch Scientific Company.

Double line variant

A dividing line between metals and nonmetals is sometimes replaced by two dividing lines. One line separates metals and metalloids; the other metalloids and nonmetals.

Concerns

Mendeleev wrote that, "It is, however, impossible to draw a strict line of demarcation between metals and nonmetals, there being many intermediate substances". Several other sources note confusion or ambiguity as to the location of the dividing line; suggest its apparent arbitrariness provides grounds for refuting its validity; and comment as to its misleading, contentious or approximate nature. Deming himself noted that the line could not be drawn very accurately.

Notes

Citations

References

Abraham M, Coshow, D & Fix, W 1994, Periodicity: A source book module, version 1.0. Chemsource, Inc., New York, viewed 26 Aug 11
Brown L & Holme T 2006, Chemistry for engineering students, Thomson Brooks/Cole, Belmont CA,
De Graef M & McHenry ME 2007, Structure of materials: an introduction to crystallography, diffraction and symmetry, Cambridge University Press, Cambridge,
Deming HG 1923, General chemistry: An elementary survey, John Wiley & Sons, New York
Emsley J, 1985 'Mendeleyev's dream table', New Scientist, 7 March, pp. 32Ã¢ÂÂ36
Glinka N 1959, General chemistry, Foreign Languages Publishing House, Moscow
Hinrichs GD 1869, 'On the classification and the atomic weights of the so-called chemical elements, with particular reference to Stas's determinations', Proceedings of the American Association for the Advancement of Science, vol. 18, pp. 112Ã¢ÂÂ124
Housecroft CE & Constable EC 2006, Chemistry, 3rd ed., Pearson Education, Harlow, England,
King RB (ed.) 2005, Encyclopedia of inorganic chemistry, 2nd ed., John Wiley & Sons, Chichester, p. 6006,
Kniep R 1996, 'Eduard Zintl: His life and scholarly work', in SM Kauzlarich (ed.), Chemistry, structure and bonding of Zintl phases and ions, VCH, New York, pp. xviiÃ¢ÂÂxxx,
Kotz JC, Treichel P & Weaver GC 2005, Chemistry & chemical reactivity, 6th ed., Brooks/Cole, Belmont, CA,
Levy J 2011, The bedside book of chemistry, Pier 9, Millers Point, Sydney,
MacKay KM & MacKay RA 1989, Introduction to modern inorganic chemistry, 4th ed., Blackie, Glasgow,
MendelÃÂ©eff DI 1897, The principles of chemistry, vol. 1, 5th ed., trans. G Kamensky, AJ Greenaway (ed.), Longmans, Green & Co., London
Miles WD & Gould RF 1976, American chemists and chemical engineers, vol. 1, American Chemical Society, Washington
Norman NC 1997, Periodicity and the s- and p-block elements, Oxford University, Oxford,
Roher GS 2001, Structure and bonding in crystalline materials, Cambridge University Press, Cambridge,
Smith A 1906, Introduction to general inorganic chemistry, The Century Company, New York
Swenson J 2005, 'Classification of noble gases', in Ask a scientist, Chemistry archive
Tarendash AS 2001, Let's review: Chemistry, the physical setting, Barron's Educational Series, Hauppauge, New York,
Walker J 1891, 'On the periodic tabulation of the elements', The Chemical News, vol. LXIII, no. 1644, May 29, pp. 251Ã¢ÂÂ253
Whitley K 2009, Periodic table: Metals, non-metals, and semi-metals
Whitten KW, Davis RE & Peck LM 2003, A qualitative analysis supplement, 7th ed., Thomson Brooks/Cole, Belmont, CA,

External links

Summary of an ACS presentation on the "myth" of the dividing line