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Dinitroglycoluril

Dinitroglycoluril (DNGU) is a high explosive chemical compound with the formula C<sub>4</sub>H<sub>4</sub>N<sub>6</sub>O<sub>6</sub>. Dinitroglycoluril is of growing interest due to its stability, ability to mix with oxygen positive explosives to form composites, and it is a precursor to tetranitroglycoluril.

Preparation and decomposition

Dinitroglycoluril can be created by nitrating glycoluril with concentrated nitric acid.

The activation energy required to begin decomposition of dinitroglycoluril is 165&nbsp;kJ/mol. When dinitroglycoluril is heated to 243&nbsp;°C in an inert atmosphere, the two nitrate groups break off and the two central carbon atoms form a double bond.

Sensitivity

The impact sensitivity of dinitroglycoluril was determined using the Bruceton-staircase procedure, which found a h<sub>50</sub> of 88&nbsp;cm. Friction sensitivity was determined by a Julius-Peters apparatus, which found a sensitivity of 25&nbsp;kg.

References