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Diiodophenylpyruvate reductase

In enzymology, a diiodophenylpyruvate reductase () is an enzyme that catalyzes the chemical reaction

3-(3,5-diiodo-4-hydroxyphenyl)lactate + NAD<sup>+</sup> 3-(3,5-diiodo-4-hydroxyphenyl)pyruvate + NADH + H<sup>+</sup>

Thus, the two substrates of this enzyme are 3-(3,5-diiodo-4-hydroxyphenyl)lactate and NAD<sup>+</sup>, whereas its 3 products are 3-(3,5-diiodo-4-hydroxyphenyl)pyruvate, NADH, and H<sup>+</sup>.

This enzyme belongs to the family of oxidoreductases, specifically those acting on the CH-OH group of donor with NAD<sup>+</sup> or NADP<sup>+</sup> as acceptor. The systematic name of this enzyme class is 3-(3,5-diiodo-4-hydroxyphenyl)lactate:NAD<sup>+</sup> oxidoreductase. Other names in common use include aromatic alpha-keto acid, KAR, and 2-oxo acid reductase.

In 2025, this enzyme was found to be identical to , (S)-malate dehydrogenase.

References