Thioxoethenylidene

Thioxoethenylidene, is a reactive heteroallene molecule with formula CCS.

Occurrence

CCS is found in space in large quantities. This includes the Taurus Molecular Cloud in TMC-1, TMC-1c and L1521B. These are likely in young starless molecular cloud cores.

Production

By condensing propadienedithione SCCCS or thioxopropadienone OCCCS in solid argon and irradiating with ultraviolet radiation, CCS is formed. Another way is via a glow discharge in a mixture of carbon disulfide and helium. Yet another way is through electron irradiation of sulfur containing heterocycles.

CCS and the anion CCS^− can be formed in solid neon matrices also.

Properties

CCS can be a ligand. It can form an asymmetrical bridge between two molybdenum atoms in Mo2(μ,σ(C):η²(C′S)-CCS)(CO)₄(hydrotris(3,5-dimethylpyrazol-1-yl)borate)₂ In this one carbon atom has a triple bond to a molybdenum and the other has a double bond to the other molybdenum atom, which also has a single bond to the sulfur atom.

The ultraviolet spectrum shows absorption bands between 2800 and 3370 ÃƒÂ… and also in the near infrared between 7500 and 10000 ÃƒÂ…. CCS can react with CCCS to form C₅S.

The infrared spectrum in solid argon shows a vibration band at 1666.6 cm^{−1} called v₁ and another called v₂ at 862.7 cm^{−1}. The 2v₁ overtone is at 3311.1  cm^{−1}. A combination vibration and bending band is at 2763.4 cm^{−1}

The microwave spectrum has emission lines 4₃ − 3₂ at 45.4 GHz and 2₁ - 1₀ at 22.3 GHz, important for detection of molecules in molecular clouds.

Theoretical predictions show that the C-C bond is 1.304 ÃƒÂ… long and the C–S bond is 1.550 ÃƒÂ….

References