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Cyclopeptine synthase

Cyclopeptine synthase () is an enzyme that catalyzes the chemical reaction

anthranilate + L-phenylalanine + S-adenosyl-L-methionine + 2 ATP cyclopeptine + 2 AMP + S-adenosyl-L-homocysteine + 2 diphosphate + 2 H(+)

In Penicillium cyclopium, cyclopeptine synthase is important for benzodiazepine alkaloid biosynthesis.

Enzyme Classification History

Formerly, cyclopentine synthase activity was classified under two separate enzymes.

  • anthranilate adenylyltransferase () catalyzes the partial reaction
ATP + anthranilate diphosphate + N-adenylylanthranilate
  • phenylalanine adenylyltransferase () catalyzes the partial reaction
ATP + L-phenylalanine diphosphate + N-adenylyl-L-phenylalanine

and were reclassified and merged into .

References