my-server
← Wiki

Citramalic acid

Citramalic acid is the organic compound with the formula HO<sub>2</sub>CCH<sub>2</sub>C(CH<sub>3</sub>)(OH)CO<sub>2</sub>H. A chiral compound, it is related structurally to malic acid.

Synthesis and reactions

Citramalic acid is the hydrated derivative of mesaconic acid, The hydration is catalyzed by mesaconyl-C4-CoA hydratase:

HO<sub>2</sub>CCH=C(CH<sub>3</sub>)CO<sub>2</sub>H + H<sub>2</sub>O → HO<sub>2</sub>CCH<sub>2</sub>C(CH<sub>3</sub>)(OH)CO<sub>2</sub>H

The same conversion can be achieved in vitro.

The enzyme (S)-citramalyl-CoA lyase converts citramalyl-CoA to acetyl-CoA and pyruvate.

References