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Boratabenzene

Boratabenzene, sometimes called borinate, is the heteroaromatic anion with the formula [C<sub>5</sub>H<sub>5</sub>BH]<sup>−</sup>.

Derivatives of boratabenzene are ligands akin to cyclopentadienyl anion. sandwich or half-sandwich type complexes of many transition metals have been reported. The 1-methyl and 1-phenyl borinates can form some of the few organo-thallium(I) compounds.

Electronically related heterocycles are adducts of the notional borabenzene. The adduct C<sub>5</sub>H<sub>5</sub>B·pyridine exhibits properties of boratabenzene anion, i.e., it has the character C<sub>5</sub>H<sub>5</sub>B<sup>−</sup>-N<sup>+</sup>C<sub>5</sub>H<sub>5</sub>.

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References