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Gold(III) acetate

Gold(III) acetate, also known as auric acetate, is a chemical compound of gold and acetic acid. It is a yellow solid that decomposes at 170 °C to gold metal. This decomposition of gold(III) acetate has been studied as a pathway to produce gold nanoparticles as catalysts.

Production and reactions

Gold(III) acetate can be produced by the reaction of gold(III) hydroxide and glacial acetic acid:

Au(OH)<sub>3</sub> + 3CH<sub>3</sub>COOH → Au(CH<sub>3</sub>COO)<sub>3</sub> + 3H<sub>2</sub>O

It reacts with 2-(p-tolyl)pyridine (tpy) in presence of trifluoroacetic acid to form Au(CF<sub>3</sub>COO)<sub>2</sub>(tpy).

Gold(III) sulfide has been claimed as the product when gold(III) acetate is sonicated with cyclo-octasulfur in decalin.

References