Volhynia Governorate, also known as Volyn Governorate, was an administrative-territorial unit (guberniya) of the Southwestern Krai of the Russian Empire, established in the historical region of Volhynia. It consisted of an area of and a population of 2,989,482 inhabitants. The governorate bordered Grodno and Minsk Governorates to the north, Kiev Governorate to the east, Podolia Governorate to the south, Lublin and Siedlce Governorates, and after 1912, Kholm Governorate and Austria to the west. Its capital was in Novograd-Volynsky until 1804, and then Zhitomir. It corresponded to most of modern-day Volyn, Rivne and Zhytomyr Oblasts of Ukraine and some parts of Brest and Gomel Regions of Belarus.
It was created at the end of 1796 after the Third Partition of Poland from the territory of the short-lived Volhynian Vice-royalty and Woà Âyà  Voivodeship. After the Peace of Riga, part of the governorate became the new Woà Âyà  Voivodeship in the Second Polish Republic, while the other part stayed as a part of the Ukrainian SSR until 1925 when it was abolished on resolution of the All-Ukrainian Central Executive Committee and Counsel of People's Commissars.
Until 1796, the guberniya was administered as a Viceroyalty (namestnichestvo). It was initially centred in Izyaslav and was called the Izyaslav Viceroyalty. It was primarily created from the Kiev Voivodeship and the eastern part of the Wolyn Voivodeship.
On 24 October 1795, the Third Partition of Poland was imposed by Prussia, the Habsburg monarchy, and the Russian Empire.
Then, on 12 December 1796, Volhynia Governorate was established, encompassing the remaining territory of the Wolyn Voivodeship and the Kowel Voivodeship.
In 1796, the administration moved to Novograd-Volynsky. However, due to the lack of suitable buildings for administrative purposes, the capital was moved once again to Zhitomir (Zhytomyr).
In 1802, Zhitomir was purchased the properties of Prince Ilyinsky, and in 1804, it officially became the seat of Volhynia Governorate.
From 1832 to 1915, Volhynia Governorate, along with Kiev Governorate and Podolia Governorate, formed part of the Southwestern Krai General-GovernorateâÂÂa militarized administrative-territorial unit.
In the 1880s, the general-governorate was extended to include other governorates.
In 1897, the population of the guberniya was 2,989,482 and by 1905, it had grown to 3,920,400. The majority of the population in the governorate spoke the Ukrainian language with slight variety of dialects.
Under the Russian Provisional Government administrative power in the governorates was transferred to commissars, who preserved their positions after the proclamation of Ukrainian People's Republic in November 1917. Their power was mostly nominal due to the growth of Bolshevik Soviet influence, especially in industrial areas. During that time served as the gubernial commissar of Volhynia.
During the UkrainianâÂÂSoviet War Zhitomir served as the provisional capital of Ukraine in 1918.
After the return of Central Rada in March 1918 new commissars were appointed along with military commandants. After the establishment of the Hetmanate, in May 1918 those were replaced with Governorate starosts.
After the Polish-Soviet war in 1920, and according to the Peace of Riga (1921) most of the territory became part of the Second Polish Republic and transformed into the Woà Âyà  Voivodeship, with the capital in à Âuck (Lutsk). The eastern portion existed until 1925 and was later split into three okruhas: Shepetivka Okruha, Zhytomyr Okruha, and Korosten Okruha.
Russian Census of 1897
According to the Russian Empire Census on , the Volhynian Governorate had a population of 2,982,482, including 1,502,803 men and 1,486,679 women. The majority of the population indicated Ukrainian to be their mother tongue, with significant Jewish, Polish, German, and Russian speaking minorities.