Tungsten hexabromide, also known as tungsten(VI) bromide, is a chemical compound of tungsten and bromine with the formula . It is an air-sensitive dark grey powder that decomposes above 200 ðC to tungsten(V) bromide and bromine.
Tungsten hexabromide is mainly produced by the reaction of metallic tungsten and bromine at temperatures around 100 ðC in a nitrogen atmosphere:
Another method of producing this compound is by the reaction of tungsten hexacarbonyl and bromine at room temperature, releasing carbon monoxide. It can also be produced by the metathesis reaction of boron tribromide and tungsten hexachloride.
is reduced with elemental antimony at elevated temperatures, consecutively producing, , , , , then finally at 350 ðC. This reaction produces antimony tribromide as a side product. Any of these bromides can be reverted to the hexabromide by oxidation with bromine at 160 ðC.
Tungsten hexabromide is hydrolyzed in water, producing tungsten pentoxide and releasing bromine.
Tungsten(VI) oxytetrabromide is produced by the reaction of tungsten hexabromide and tungsten(VI) oxide:
The trigonal crystal structure of consists of isolated octahedra and is isostructural with ñ-.