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Thorium diiodide

Thorium diiodide is an iodide of thorium, with the chemical formula of ThI<sub>2</sub>. It is an electride with the ionic formula Th<sup>4+</sup>(I<sup>−</sup>)<sub>2</sub>e<sup>−</sup><sub>2</sub>. It is air-sensitive.

Preparation

Thorium diiodide cn be prepared by heating thorium tetraiodide in stoichiometric amounts of thorium:

It can also be prepared by directly reacting thorium and iodine:

Thorium diiodide can also be prepared from the decomposition of thorium triiodide at temperatures above 550&nbsp;°C:

Properties

Like the diiodides of cerium, praseodymium and gadolinium, it has a metallic gold lustre and high electrical conductivity.

References