Slovenia competed in the Summer Olympic Games for the first time at the 1992 Summer Olympics in Barcelona, Spain. It was the first Olympiad after Slovenia seceded from Yugoslavia. 35 competitors, 29 men and 6 women, took part in 34 events in 12 sports.
The following is the list of number of competitors in the Games.
In Slovenia's first archery competition, the nation entered one archer. He narrowly missed qualifying for the elimination rounds.
One male cyclist represented Slovenia in 1992.