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Scandium monosulfide

Scandium monosulfide is a chemical compound of scandium and sulfur with the chemical formula ScS. Although its formula might suggest that it is a compound of scandium(II), i.e. [Sc<sup>2+</sup>][S<sup>2−</sup>], ScS is probably more realistically described as a pseudo-ionic compound, containing [Sc<sup>3+</sup>][S<sup>2−</sup>], with the remaining electron occupying the conduction band of the solid.

Structure

Scandium monosulfide adopts the sodium chloride crystal structure type.

Synthesis

Scandium monosulfide can be prepared by heating a mixture of scandium metal and powdered sulfur in the absence of air to 1150&nbsp;°C for 70 hours.

Sc + S → ScS

References