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S-Nitrosotriphenylmethanethiol

S-Nitrosotriphenylmethanethiol is the organosulfur compound with the formula (C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>CSNO. It is a rare example of a nitrosothiol derivative that is robust solid at room temperature. The green compound can be produced by the reaction of triphenylmethanethiol with nitrous acid:

(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>CSH + HONO → (C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>CSNO + H<sub>2</sub>O

According to X-ray crystallography, S-nitrosotriphenylmethanethiol features a conventional trityl group appended to a bent SNO substituent. The S-N=O angle is 114°, while the S-N and N=O distances are 1.78 and 1.79 Å. Other S-nitrosothiols, e.g. MeSNO and SNAP have characterized by similar structures.

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