Rhodium acetylacetonate is the coordination complex with the formula , which is sometimes known as Rh(acac)<sub>3</sub>. The molecule has D<sub>3</sub>-symmetry. It is a yellow-orange solid that is soluble in organic solvents.
It is prepared from RhCl<sub>3</sub>(H<sub>2</sub>O)<sub>3</sub> and acetylacetone. The complex has been resolved into individual enantiomers by separation of its adduct with dibenzoyltartaric acid.