Congo competed at the 2014 Summer Youth Olympics, in Nanjing, China from 16 August to 28 August 2014.
Congo qualified one athlete.
<small>Qualification Legend: Q=Final A (medal); qB=Final B (non-medal); qC=Final C (non-medal); qD=Final D (non-medal); qE=Final E (non-medal)</small>
Congo was given a quota to compete by the tripartite committee.
Congo qualified a boys' and girls' team by their performance at the CAVB Qualification Tournament.
Congo was given a quota to compete by the tripartite committee.
<small>Qualification Legend: Q=Main Bracket (medal); qB=Consolation Bracket (non-medal)</small>
Congo was given an invitation to compete from the Tripartite Commission.
Key: