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Quantum paraelectricity

Quantum paraelectricity is a type of incipient ferroelectricity where the onset of ferroelectric order is suppressed by quantum fluctuations. From the soft mode theory of ferroelectricity, this occurs when a ferroelectric instability is stabilized by quantum fluctuations. In this case the soft-mode frequency never becomes unstable (Fig. 1a) as opposed to a regular ferroelectric.

Experimentally this is associated with an anomalous behaviour of the dielectric susceptibility, for example in SrTiO<sub>3</sub>. In a normal ferroelectric, close to the onset of the phase transition the dielectric susceptibility diverges as the temperature approaches the Curie temperature. However, in the case of a quantum paraelectric the dielectric susceptibility diverges until it reaches a temperature low enough for quantum effects to cancel out the ferroelectricity (Fig. 1b). In the case of SrTiO<sub>3</sub> this is around 4K.

Other known quantum paraelectrics are KTaO<sub>3</sub> and potentially CaTiO<sub>3</sub>.

References