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Neodymium(III) hydroxide

Neodymium(III) hydroxide is an insoluble inorganic compound with the chemical formula Nd(OH)<sub>3</sub>.

Preparation

Neodymium(III) nitrate and ammonia water will react to produce neodymium(III) hydroxide:

Nd(NO<sub>3</sub>)<sub>3</sub> + 3 NH<sub>3</sub>·H<sub>2</sub>O → Nd(OH)<sub>3</sub>↓ + 3 NH<sub>4</sub>NO<sub>3</sub>

If the amount of Nd(NO<sub>3</sub>)<sub>3</sub> is 40g/L, the amount of ammonia water needed is 0.50&nbsp;mol/L. The ammonia water is mixed into the Nd(NO<sub>3</sub>)<sub>3</sub> solution at the speed of 1.5mL/min, and polyethylene glycol is used to control pH. The process will produce neodymium(III) hydroxide powder with grain size ≤1μm.

Chemical properties

Neodymium(III) hydroxide can react with acid and produce neodymium salts:

Nd(OH)<sub>3</sub> + 3 H<sup>+</sup> → Nd<sup>3+</sup> + 3 H<sub>2</sub>O

For example, to create neodymium acetate with neodymium(III) hydroxide:

Nd(OH)<sub>3</sub> + 3CH<sub>3</sub>COOH → Nd(CH<sub>3</sub>COO)<sub>3</sub> + 3H<sub>2</sub>O

See also

References