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N-Formylpiperidine

N-Formylpiperidine is an organic compound with the formula C<sub>6</sub>H<sub>11</sub>NO. It is the amide of formic acid and piperidine. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide (DMF). It has also been used to transfer the formyl group to a Grignard reagent:

PhCH<sub>2</sub>CH<sub>2</sub>MgCl + C<sub>6</sub>H<sub>11</sub>NO → PhCH<sub>2</sub>CH<sub>2</sub>CHO

In some formylation reaction of alkyllithium compounds, N-formylpiperidine gives higher yields than the DMF.

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