James or Jim Alexander may refer to:
Arts and entertainment
Law and politics
- James Alexander (lawyer) (1691âÂÂ1756), American lawyer and politician of the colonial period
- James Alexander, 1st Earl of Caledon (1730âÂÂ1802), Irish landlord, merchant, politician and peer of the realm
- James Alexander (1769âÂÂ1848), British banker, and MP for Old Sarum
- James Alexander Jr. (1789âÂÂ1846), U.S. Congressman from Ohio
- James Alexander, 3rd Earl of Caledon (1812âÂÂ1855), British soldier and politician
- James M. Alexander (1815âÂÂ1871), African-American businessperson and politician in Arkansas
- James Peterkin Alexander (1835âÂÂ1912), Scottish-born politician in Manitoba, Canada
- James Alexander, 4th Earl of Caledon (1846âÂÂ1898), British soldier and politician
- James P. Alexander (1883âÂÂ1948), American jurist, Justice of the Supreme Court of Texas
- James Alexander Anderson (died 1930), Canadian politician
Others