Iodine trifluoride dioxide is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula . The compound was first obtained by Engelbrecht and Petersy in 1969.
Iodine trifluoride dioxide may be formed by the reaction of and oleum.
Iodine trifluoride dioxide forms yellow volatile crystals, which melt at 41 ðC. Decomposes under direct sunlight or heating.
The molecules in the crystals are dimers. The compound is monomeric above 100 ðC.
Iodine trifluoride dioxide decomposes when heated: