The Waikato and King Country regions of New Zealand are built upon a basement of greywacke rocks, which form many of the hills. Much of the land to the west of the Waikato River and in the King Country to the south has been covered by limestone and sandstone, forming bluffs and a karst landscape. The volcanic cones of Karioi and Pirongia dominate the landscape near Raglan and Kawhia Harbours. To the east, the land has been covered with ignimbrite deposits from the Taupà  Volcanic Zone. Large amounts of pumice from the Taupà  Volcanic Zone have been deposited in the Waikato Basin and Hauraki Plains.
As with most of New Zealand, the basement rocks of the Waikato Region and King Country are composed of greywacke (indurated sandstone, siltstone and mudstone).
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The Waipa Fault passes northâÂÂsouth through the Waikato-King Country region, from Taupiri, along the WaipàRiver, and south to near à Âhura. It represents a major dividing line between different terranes.
Murihiku terrane greywacke lies beneath the WaikatoâÂÂKing Country region on the western side, and outcrops to the west of the Waipa Fault, from south of Waikato Heads to Awakino. The Murihiku terrane is considered to be an accretionary wedge of mainly volcanogenic forearc sediments. It was formed in Late Triassic to Late Jurassic times (220-145 Ma).
A line of Dun MountainâÂÂMaitai terrane rocks are assumed to pass northâÂÂsouth along the Waipa Fault, through the centre of the Waikato-King Country region, separating the Murihiku terrane and Waipapa composite terrane, and produce a detectable junction magnetic anomaly, but only outcrops at one place, at Wairere. Some Murihiku rocks occur to the east of the junction magnetic anomaly, forming the Taupiri and Hakarimata Ranges, but it is assumed that these rocks have been shifted to their present position.
The Waipapa Morrinsville terrane greywacke lies beneath the WaikatoâÂÂKing Country region on the eastern side, south of the Hunua Ranges, and east of the Waipa Fault. It was formed in Late Jurassic to early Cretaceous times (160âÂÂ120 Ma).
The Te Kuiti Group rocks overlie the basement rocks, and are present in Northland, Auckland, the Waikato, and King Country, although they have often been eroded or covered. Rocks containing coal were formed from swampland in Late Eocene times (37-34 Ma). The land sunk and the sea transgressed, and calcareous sandstone, mudstone, and limestone were deposited in Oligocene times (34-24 Ma).
The coal deposits outcrop near Huntly and Maramarua, where they are mined.
Limestone exists in the area south and west of the Waikato River, down to Piopio and Te Kà «iti, producing impressive bluffs around Port Waikato, Raglan Harbour, Kawhia Harbour, Otorohanga, Waitomo, Te Kà «iti, etc. The Karst landscape around Waitomo contains many cave systems, including the Waitomo Glowworm Cave.
In early Miocene times (24 Ma), plate convergence caused regional compression. The land eroded, and was deposited throughout the Miocene (24-5 Ma) in rapidly subsiding basins. These soft sandstones and mudstones remain to the southwest of Te Kà «iti.
The volcanic arc that developed to the west of Northland and Auckland extended further south towards Taranaki. These andesitic and basaltic volcanoes were mostly active in middle Miocene times (14-11 Ma), and contributed volcanics that are found interleaved in the sandstone and mudstone deposits that formed around that time.
Mount Karioi and Mount Pirongia, near Raglan and Kawhia Harbours, are large stratovolcanoes composed of andesite and basalt, that erupted about 2.5 Ma ago. Other volcanoes in this group include Kakepuku, Te Kawa, and Tokanui.
Maungatautari, west of Te Awamutu, is a volcano, composed of andesite and dacite, that erupted about 1.8 Ma.
Over the last 2 million years, pyroclastic flows from the Taupà  Volcanic Zone have deposited ignimbrites over the area east of Te Kà «iti. Some of the largest deposits are from the Whakamaru eruption, north of Taupà Â, around 330,000 years ago. The ignimbrite deposits from the Oruanui eruption 26,500 years ago, and the Taupà  eruption, 1800 years ago are also major deposits. They form impressive cliffs in many areas.
The Hauraki Plains and Hauraki Gulf represent a rift valley. The rift valley is assumed to have developed about 2 Ma ago, due to the clockwise rotation of the Eastern North Island, that stretched the land between Auckland and East Cape. This rotation may also have been associated with rifting that created the Hamilton Basin to their south west.
The Waikato River used to flow from Lake Karapiro, through the Hinuera Gap, and Hauraki Plains, to come out on the east coast in the Hauraki Gulf. The sediment from the 26.5 ka Oruanui eruption of Lake Taupà  caused the river to change direction, and come out to the west. In fact, the Waikato River changes its route quite regularly, as eruptions occur in the Taupà  Volcanic Zone, and the river channel becomes blocked. Many lakes and swamps in the Waikato Basin represent old routes.
Pumice from the Taupà  Volcanic Zone has been deposited throughout the Waipa and Waikato Basins, and the Hauraki Plains, forming excellent soils and swampland.
Tauranga Group describes sediments of the last 5 million years, mainly of volcanic pumice, initially Pliocene deposits (Walton Subgroup) from Coromandel and latterly Holocene from Taupà  (Piako Subgroup). They underlie the Hamilton lowlands and extend into the Waipa basin, but elsewhere are mainly alluvial deposits in valleys. As well as pumice gravels and sands, they include silts, muds and peat.
Substantial sand dunes with high iron content have formed around the Kawhia and Aotea Harbours.
David Kear's 'Geology of Ironsand Resources of New Zealand' (NZ Dept of Scientific & Industrial Research 1979) says, "The ironsand deposits extend from south Kaipara and Muriwai, north of Auckland, for over 300 miles southwards to the Whangaehu River, south of Wanganui". Soluble iron in concentrates exceeds 50% in most locations. It is currently mined at Taharoa and Waikato North Head.
Geological maps of New Zealand are now freely accessible on line from the New Zealand Institute of Geological and Nuclear Science (GNS Science), a New Zealand Government Research Institute.