my-server
← Wiki

Duroquinone

Duroquinone is an organic oxidant (C<sub>6</sub>(CH<sub>3</sub>)<sub>4</sub>O<sub>2</sub>). It is related to 1,4-benzoquinone by replacement of four H centres with methyl (Me) groups. The C<sub>10</sub>O<sub>2</sub> core of this molecule is planar with two pairs of C=O and C=C bonds.

The compound is produced via nitration of durene (1,2,4,5-tetramethylbenzene) followed reduction to the diamine and then oxidation.

A derived organoiron compound (η<sup>2</sup>,η<sup>2</sup>-C<sub>6</sub>(CH<sub>3</sub>)<sub>4</sub>O<sub>2</sub>)Fe(CO)<sub>3</sub> is obtained by the carbonylation of 2-butyne in the presence of iron pentacarbonyl.

The molecule has been mentioned in the popular press as a component of a "nano brain".

Duroquinone was observed in a degradation products generated from pyrolysis of α-Tocopheryl acetate.

References