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Cyaarside

Cyaarside, also called cyarside, is the anion. Featuring a triple bond between arsenic and carbon, it is the arsenic analogue of cyanide and cyaphide.

Preparation

An actinide cyaarside complex can be prepared by C−O bond cleavage of the arsaethynolate anion , the arsenic analogue of cyanate and phosphaethynolate. Reaction of the uranium complex [] with one molar equivalent of [ in the presence of 2.2.2-cryptand results in the formation of a dinuclear, oxo-bridged uranium complex featuring a C≡As ligand.

See also

References