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Actinium(III) fluoride

Actinium(III) fluoride (AcF<sub>3</sub>) is an inorganic compound, a salt of actinium and fluorine.

Synthesis

Actinium fluoride can be prepared in solution or by a solid-state reaction. In the first method, actinium hydroxide is treated with hydrofluoric acid and the product precipitates:

In the solid-state reaction, actinium metal is treated with hydrogen fluoride gas at 700&nbsp;°C in a platinum crucible.

Properties

Actinium fluoride is a white solid that reacts with ammonia at 900–1000&nbsp;°C to yield an actinium oxyfluoride:

AcF<sub>3</sub> + 2NH<sub>3</sub> + H<sub>2</sub>O -> AcOF + 2NH<sub>4</sub>F

While lanthanum oxyfluoride is easily formed by heating lanthanum fluoride in air, a similar treatment merely melts actinium fluoride and does not yield AcOF.

References