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2-Naphthalenethiol

2-Naphthalenethiol is an organosulfur compound with the formula C<sub>10</sub>H<sub>7</sub>SH. It is a white solid. It is one of two monothiols of naphthalene, the other being 1-naphthalenethiol.

Synthesis and reactions

2-Naphthalenethiol is prepared from 2-naphthol by the Newman–Kwart rearrangement starting from a thiocarbamate. It undergoes lithiation at the 1 and 3-position.

It can be used as a flavouring agent and has been described as having an “artichoke”, “meaty” and “creamy” taste”.

References