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1,2-Diiodoethane

1,2-Diiodoethane is an organoiodine compound.

Preparation and reactions

1,2-Diiodoethane can be prepared by the reaction of ethylene with iodine (I):

CH + I CHI

1,2-Diiodoethane is most commonly used in organic synthesis in the preparation of samarium(II) iodide or ytterbium(II) iodide in an inert solvent such as THF.

Sm + ICH<sub>2</sub>CH<sub>2</sub>I → SmI<sub>2</sub> + H<sub>2</sub>C=CH<sub>2</sub>

Spectral properties

In mass spectroscopy, 1,2-diiodoethane exhibits 5 major peaks, with the base peak showing at 155 m/z, which is the loss of one iodine atom (127 m/z).

References