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(Norbornadiene)molybdenum tetracarbonyl

(Norbornadiene)molybdenum tetracarbonyl is the organomolybdenum compound with the formula (C<sub>7</sub>H<sub>9</sub>)Mo(CO)<sub>4</sub>. Structurally, the compound consists of the norbornadiene bonded to a Mo(CO)<sub>4</sub> fragment. The compound is a yellow, volatile solid. It is prepared by thermal or photochemical substitution of molybdenum hexacarbonyl. The compound was originally examined as a potential antiknock agent.

(Norbornadiene)molybdenum tetracarbonyl is a precursor to other derivatives of the type L<sub>2</sub>Mo(CO)<sub>4</sub>. This conversion exploits the lability of the diene ligand:

(C<sub>7</sub>H<sub>9</sub>)Mo(CO)<sub>4</sub> + 2 L → C<sub>7</sub>H<sub>9</sub> + L<sub>2</sub>Mo(CO)<sub>4</sub>

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